Energy Flow in the Nano Range
October 22, 2019 | JMU WürzburgEstimated reading time: 2 minutes
It is crucial for photovoltaics and other technical applications, how efficiently energy spreads in a small volume. With new methods, the path of energy in the nanometer range can now be followed precisely.
Plants and bacteria lead the way: They can capture the energy of sunlight with light-harvesting antennas and transfer it to a reaction centre. Transporting energy efficiently and in a targeted fashion in a minimum of space—this is also of interest to mankind. If scientists were to master it perfectly, they could significantly improve photovoltaics and optoelectronics.
Two new spectroscopic methods
But how can the flow of energy be observed? This is what Tobias Brixner's group at the Institute of Physical and Theoretical Chemistry at Julius-Maximilians-Universität (JMU) Würzburg in Bavaria, Germany, is working on.
In the journal Nature Communications, the team now presents two new spectroscopic methods with which energy transport on the nanoscale can be observed. According to the JMU professor, the new findings provide valuable information for the design of artificial light-harvesting antennas.
These research successes were achieved in cooperation with the working groups of Christoph Lambert and Todd Marder (JMU Würzburg), Uwe Bunz and Andreas Dreuw (University of Heidelberg) as well as Jasper Knoester and Maxim Pshenichnikov (University of Groningen, Netherlands).
Nanotubes imitate nature
Using the new methods, the research teams have succeeded in deciphering the energy transport in double-walled nanotubes made up of thousands of dye molecules. These tiny tubes serve as models for the light-harvesting antennas of photosynthetically active bacteria.
At low light intensities, the energetic excitations are transported from the outer to the inner wall of the tubes. At high intensities, on the other hand, the excitations only move along the outer wall—if two excitations meet there, one of them disappears. "This effect, which has been known for some time, can be made directly visible with our method for the first time," says Brixner.
The measurements could be carried out by combining the exciton-exciton-interaction-two-dimensional spectroscopy (EEI2D spectroscopy) method developed in the Brixner group with a microfluidic arrangement of the Groningen group.
Data acquisition is much faster
In the second paper, the research teams also demonstrate a new approach to measuring energy flows. The highlight: The speed of the data recording could be extremely increased compared to the state of the art. Within just eight minutes, it was possible to measure up to 15 different 3D spectra simultaneously in a single experiment. Traditional methods, on the other hand, typically require several hours for only a single spectrum.
As a basis for measuring coherent spectra over three frequency dimensions, the researchers employed a fast method of varying the temporal sequence of ultrashort laser pulses. "The expansion from 2D to 3D frequency analysis and the increase in the number of light-matter interactions from the four usual in the literature to six now provides detailed insights into the dynamics of highly excited states," says Brixner.
Suggested Items
Boeing Opens Research & Technology Center in Japan
04/23/2024 | BoeingBoeing today opened a Boeing Research & Technology (BR&T) Center in Japan that will focus on innovation to enable the commercial aviation industry meet its goal of net zero carbon emissions by 2050.
Gartner Forecasts Worldwide IT Spending to Grow 8% in 2024
04/17/2024 | Gartner, Inc.Worldwide IT spending is expected to total $5.06 trillion in 2024, an increase of 8% from 2023, according to the latest forecast by Gartner, Inc. This is an increase from the previous quarter’s forecast of 6.8% growth and puts worldwide IT spending on track to surpass $8 trillion well before the end of the decade.
Argonne, RIKEN Sign a Memorandum of Understanding in Support of AI for Science
04/16/2024 | BUSINESS WIRELeaders in high performance computing in the U.S. and Japan have signed a memorandum of understanding (MOU) establishing a cooperative relationship in support of artificial intelligence (AI) computing projects.
RAICo Fellowship to Widen Participation Within the Field of Robotics and Artificial Intelligence
04/12/2024 | RAICoWOMEN and those early in their academia career who are passionate about robotics and artificial intelligence are encouraged to apply for a RAICo Fellowship.
Indium to Host Free Webinar on Lead-Free Solder Paste for Automotive Applications
04/09/2024 | Indium CorporationIndium Corporation’s Senior Research Metallurgist, Jie Geng, Ph.D., will conduct a webinar on low-voiding, high-reliability, lead-free solder paste for automotive applications.