Plastic Crystals Could Improve Fabrication of Memory Devices
August 31, 2016 | Hokkaido UniversityEstimated reading time: 1 minute
Applying an electric field to some materials causes their atoms to "switch" their electric polarization from one direction to another, making one side of the material positive and the other negative. This switching property of "ferroelectric" materials allows them to be used in a wide range of applications. For example, ferroelectric capacitors are used to store binary bits of data in memory devices.
The newly synthesized crystal is ferroelectric above room temperature (a-b, e-f) and turns into "plastic phase", meaning highly deformable, at higher temperature (a to c). The electric polarity of each molecule can be aligned in one direction by applying electric field as it cools (c to e).
Researchers at Japan's Hokkaido University have developed a novel ferroelectric plastic crystal that could accelerate the development of more flexible, cost-efficient and less toxic ferroelectrics than those currently in use.
The crystal is ferroelectric above room temperature, then turns into a plastic, more pliable phase at higher temperatures. At the higher temperatures, the molecules in the crystal have randomly different polarity axes, but they can be aligned in one direction by applying an electric field as the crystal cools, bringing it back to a ferroelectric state.
Being able to control the polarity in this manner addresses a major challenge previously faced by researchers working with organic compound-based ferroelectric crystals. These are less symmetric than inorganic crystals, and can thus be polarized only in one direction leading to a very weak overall polarization of randomly oriented crystals.
A distinct advantage of this particular crystal is its transition to a plastic state when heat is applied. This plasticity - as opposed to fracturing that occurs in regular organic and inorganic crystals when a mechanical stress is applied - makes it extremely advantageous for use as a thin ferroelectric film in devices, such as non-volatile ferroelectric random-access memory devices, which maintain memory when the power is turned off.
Exploring crystals composed of molecules similar to quinuclidine could lead to the discovery of more ferroelectric crystals, write the researchers in their paper published in the journal Nature Chemistry. Chemical modifications of the molecules' constituent ions could also improve their performance, the researchers add.
Suggested Items
New Book on Low-temperature Soldering Now Available
04/17/2024 | I-Connect007I-Connect007 is pleased to announce that The Printed Circuit Assembler’s Guide to… Low-temperature Soldering, Vol. 2, by subject matter experts at MacDermid Alpha Electronics Solutions, is now available for download.
The Chemical Connection: Reducing Etch System Water Usage, Part 1
04/05/2024 | Don Ball -- Column: The Chemical ConnectionWater conservation has become an important component of the overall system design for most manufacturing operations today. Changing climate conditions and increasing populations are beginning to strain the freshwater supplies in many areas of the country. As a result, as equipment suppliers, we see an increasing number of requests for options that reduce water usage in proposed wet processing systems. Etching systems tend to use more water because of the need for close temperature control to maintain steady etch rates and the rinsing requirements for complete removal of corrosive etchants from the surface of the product before the next process step. This column contains some simple suggestions for reducing water usage in etch systems that won’t strain the budget too much.
Indium’s Sze Pei Lim to Present on Semiconductor Packaging at ICEP Japan
04/02/2024 | Indium CorporationIndium Corporation’s Senior Global Product Manager for Semiconductor and Advanced Materials, Sze Pei Lim, is scheduled to present at the International Conference on Electronics Packaging (ICEP 2024).
Nihon Superior Sets New Standards in Lead-Free Soldering Technology at APEX 2024
03/13/2024 | PVANihon Superior Co. Ltd., an advanced joining material supplier, will exhibit in Booth 1325 during the 2024 IPC APEX EXPO, scheduled to take place April 9-11, 2024 at the Anaheim Convention Center in California.
Indium Corporation to Showcase Proven EV Products and High-Reliability Alloys at Productronica China
02/28/2024 | Indium CorporationAs a materials pioneer and trusted partner in electric vehicle (EV) and e-Mobility manufacturing, Indium Corporation is proud to showcase its high-reliability alloys and soldering solutions at Productronica China, March 20-22, in Shanghai.